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Le, T. Q., Oliver, R. M., Arcari, J. T., & Mitton-Fry, M. J. (2012). Total synthesis of (+/-)-monomorine. Tetrahedron Letters, 53(42), 5660-5662. https://doi.org/10.1016/j.tetlet.2012.08.041
An efficient, two-operation synthesis of the trail ant pheromone (+/-)-monomorine is reported. The synthesis features an aqueous Claisen-Schmidt condensation followed by the stereocontrolled installation of the three resident stereocenters in a single operation. (C) 2012 Elsevier Ltd. All rights reserved.