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Preparation of siloxacyclopentene containing 1,3-dienes and their Diels-Alder reactions
Pidaparthi, R., & Welker, ME. (2007). Preparation of siloxacyclopentene containing 1,3-dienes and their Diels-Alder reactions. Tetrahedron Letters, 48(44), 7853-7856. https://doi.org/10.1016/j.tetlet.2007.08.133
A number of enynyloxy dimethyl and diisopropyl silanes have been prepared and converted into siloxacyclopentene containing 1,3-dienes via intramolecular hydrosilylation of the alkyne functional group. Diels-Alder reactions of these dienes are reported. (C) 2007 Elsevier Ltd. All rights reserved