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Kinetics of pentaamminenitritocobalt(III) to pentaaminenitrocobalt(III) linkage isomerization, revisited
Bodnar, W., Choi, S., & Larrabee, J. (1990). Kinetics of pentaamminenitritocobalt(III) to pentaaminenitrocobalt(III) linkage isomerization, revisited. Journal of Chemical Education, 67(3), 267-269. Article 10.102/ed067p267.
A rigorous kinetics analysis experiment using infared and visible absorption spectroscopy is feasible for an advanced undergraduate student and leads to the determination of the forward rate constant, reverse rate constant, and equilibrium constant in both the solid and solution phase reactions.